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Transformations of 1,1,2,2-tetrachloroethane under methanogenic conditions

Article Abstract:

Biotic and abiotic transformations of 1,1,2,2-tetrachloroethane (TeCA) under methanogenic conditions were investigated. It was shown that the degradation of TeCA began without lag with municipal digester sludge. Biotic transformation produced 1,1,2-trichloroethane, trans-1,2-dichloroethene and cis-1,2-dichloroethene while Abiotic degradation produced trichloroethene. Under methanogenic conditions, dichloroelimination and dehydrochlorination were both instrumental in the removal of TeCA and 1,1,2-TCA.

Author: Ferguson, John F., Chen, Chun, Puhakka, Jaako A.
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1996
Environmental aspects, Water, Underground, Groundwater, Solvents

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Effect of hydrogen on reductive dechlorination of chlorinated ethenes

Article Abstract:

Hydrogen (H2) is an important electron donor in the reductive dechlorination of chloroethenes. In a study conducted in a methanogenic fluidized bed reactor operating over 14 months, it was found that tetrachloroethene was dechlorinated at a faster rate when H2 levels increased. Additionally, dechloronating bacteria had high levels of H2 utilization than methanogens

Author: Stensel, H. David, Ferguson, John F., Ballapragada, Bhaskar S., Puhakka, J. A.
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1997
Research and Development in the Physical, Engineering, and Life Sciences, Industrial Gas Manufacturing, Industrial gases, Hydrogen, Water Pollution Control R&D, Oxidation-reduction reaction, Oxidation-reduction reactions, Water pollution research, Vinyl chloride

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Chlorophenol toxicity removal and monitoring in aerobic treatment: recovery from process upsets

Article Abstract:

A study has tested the use of an aerobic fluidized-bed reactor for bioremediation of ground water containing chlorophenols. The experiment achieved over 99% removal of stable chlorophenol. Investigation established mineralization of chlorophenols had occurred. The Microtox acute toxicity assay monitored chlorophenol degradation.

Author: Makinen, Paivi, Theno, Thomas J., Ferguson, John F., Ongerth, Jerry E., Puhakka, Jaakko A.
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1993
Health aspects, Bioremediation, Chlorophenols

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