Chemical reaction of nitric oxides with the 5-IDB defect of the single-walled carbon nanotube
Article Abstract:
The chemical reactivity of the 5-1DB defects are assessed from the analyses of the frontier molecular orbitals (FMOS) and local density of states (LDOS) and the reaction of nitric oxides (NOs) with the 5-1DB defects on the single-walled carbon nanotube (SWCNT) is described. It is indicated that the 5-1DB defects on the SWCNT is chemically reactive and can be used as the active site for the functionalization of SWCNT.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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Photoassisted adsorption of allylamine and 1-butene on H:Si(111) studied by surface vibrational spectroscopies
Article Abstract:
Ultraviolet photoadsorption of allylamine and 1-butene on hydrogen terminated Si(111) was performed by delivery of the reactant gases in an ultrahigh-vacuum (UHV) environment. The N-H bonds in allylamine were evidenced to survive over the photoadsorption process by vibrational analysis and by the reaction with ketene.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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FTIR and reaction kinetics studies of the Hydrodehalogenation of CF2Br2, CH2Br2, and CDBr2 over a Pd/gamma-Al2O3 catalyst
Article Abstract:
The hydrodehalogenation of CF2Br2, CH2Br2, and CDBr2 catalyzed by Pd/gamma-Al2O3 catalyst was investigated by a combination of FTIR and chemical reaction studies. Compared to :CH2 carbenes, the :CF2 species are unstable at room temperature on the Pd surface and tend to decompose in the absence of coadsorbed H atoms.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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