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Chemicals, plastics and rubber industries

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AFM force measurements between SAM-modified substrate in alkaline solution

Article Abstract:

The reversible desorption and adsorption of ethanethiol (ET) and hexadecane thiol (HDT) self-assembled monolayers (SAMs) on gold substrates are addressed with potential-dependent atomic force microscopy (AFM) force measurements where both tip and substrate potentials are controlled. The adhesion interaction between HDT-modified tip and substrate exhibits a large adhesion, whereas the adhesion is reduced to one-quarter of its original value after HDT on the substrate is removed.

Author: Gewirth, Andrew A., Han-Cheol Kwon
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
Mercaptans, Usage, Atomic force microscopy, Thiols

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Changing molecular orientation in fluorocarbon thin films deposited by different photo-processing: synchrotron radiation etching vs. laser ablation

Article Abstract:

Flexible macromolecule poly (tetrafluoroethylene) (PTFE) has shown its unique capacity for crystallization and molecular orientation, where it forms long extended-chain crystalline whiskers and well orients in its thin films. The study indicates that like laser ablation, synchrotron radiation (SR) can be used to directly etch materials without using any chemicals, offering a simple and versatile method for forming thin films.

Author: Zhang, Y., Katoh, T., Endo, A.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Fluorocarbons, Analysis, Magnetic properties, Synchrotron radiation

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Electronic structure of metal-free porphyrazines in thin films

Article Abstract:

Photoemission spectra of the valence region for a series of linearly benzo-annelated porphyrazine molecules in thin films using synchrotron radiation is studied for three different ligand sizes. A small influence of the tert-butyl substituent group on the photoemission spectra is observed as compared to spectra of unsubstitutted molecules.

Author: D. Pop, B. Winter, W. Freyer, I.V. Hertel, W. Widdra
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
Cyclic Crude and Intermediate Manufacturing, Porphyrins, Mechanical properties, Spectra (Spectroscopy)

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Subjects list: Research, Thin films, Dielectric films, Chemical properties
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