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Chemicals, plastics and rubber industries

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Molecular orientations in azopolymer holographic diffraction gratings as studied by Raman confocal microspectroscopy

Article Abstract:

A study was conducted to analyze molecular orientations in azopolymer holographic diffraction gratings by Raman confocal microspectroscopy. Thin films were made by spin coating a chloroform solution of the copolymer onto a microscope glass substrate. The Labram I microspectrometer was utilized to record the Raman spectra. Results indicated that the corresponding entropy distribution functions were different in several regions of the grating.

Author: Buffeteau, T., Sourisseau, C., Labarthet, F. Lagugne
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1998
Usage, Molecular dynamics, Raman spectroscopy, Semiconductor films

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Azopolymer holographic diffraction gratings: time dependent analyses of the diffraction efficiency, birefringence, and surface modulation induced by two linearly polarized interfering beams

Article Abstract:

Experiments were conducted to investigate the diffraction efficiency, birefringence, and surface modulation azopolymer films of p(DR1M-co-MMA) with a 12% mole fraction of DR1M. Parallel and perpendicular linearly polarized pump beams under low irradiances were used to record the holographic diffraction gratings. Results indicated that a nearly pure birefringence grating always form at short irradiation time.

Author: Buffeteau, T., Sourisseau, C., Labarthet, F. Lagugne
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
Refraction, Double, Double refraction

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Subjects list: Research, Thin films, Diffraction gratings
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